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Fluoropolymers top
Type of Fluoropolymers
Kinds of Fluoropolymers
Features table of Polymers
Safe Handling for Use
POLYFLON PTFE
NEW POLYFLON PTFE
NEW POLYFLON APV
NEOFLON FEP
NEOFLON ETFE
NEOFLON EFEP
NEOFLON FMC
NEOFLON PFA SH Series
Products
Fluoropolymers
Fluoropolymers Films
Additives
Fluoroelastmer
Fluoro Coatings and Paints
High Performance Chemicals
Surface Functioning Chemicals
Semiconductor Materials
Fluorocarbon

In comparison to other polymers,fluoropolymer excel in heat,chemical and weather resistance. Other than that,they have very unique characteristics such as non-stick property and low friction.They are widely used in production equipment,piping and tanks to improve efficiency and purity,protect equipment and ensure maintenance-free running under harsh conditions.

Note: Excluding the United States and Taiwan, "POLYFLON" is used as our PTFE trademark. In the United States, the PTFE trademark is "DAIKIN-POLYFLON" and in Taiwan the trademark is "DAIKIN PTFE."


POLYFLON PTFE (PTFE)
Of all the fluoroplastics products, PTFE offers the highest heat resistances at 260℃(maximum temp. for continuous use). It is not corroded by most chemicals and has good electrical insulation and dielectric characteristics. Moreover, it has a unique non-stick property and the lowest coefficient of friction amongst solids.
It is the most widely used fluoroplastics, now found in O-rings, gaskets, bearings, tube, wiring, hot plates and irons for its non-stick property, as well as chemical tank linings. A diversified product lineup is available for selection according to characteristics required by final products or production method. Daikin has also developed a next generation PTFE - New POLYFLON PTFE - that draws from the characteristics of fluorine to offer improved workability and creep property. It is meeting the needs in a wide range of fields and applications beginning with semiconductors and machines.
Name
Formula
Type
(1) (2) (3) (4) Major application
POLYFLON PTFE
Polytetra-
fluoroethylene
(PTFE)
Molding Powders


Packing,gasket,tube
Filled Molding Powders


Applications requiring mechanical strength
Fine Powders


Unsintered(raw)tape for electrical wire,tube
Filled Fine Powders


Applications requiring mechanical strength
Dispersions


Non-adhesive slide coating,impregnation to glass fabric
Enamels(*)


Non-adhesive slide coating for industrial and household equipment
Tough Coat Enamels


Abrasion resistant non-cohesive slide coating
Paste

Sealing additive,masking material
Paper


Filter medium,diaphragm,bearing for light loads
(1)For molding(2)For coating(3)For additive(4)Other use

NEOFLON PFA (PFA)
PFA exhibits thermal characteristics similar to PTFE, being able to withstand super low to high temperatures (260℃maximum temp. for continuous use ). It is also transparent and mechanically strong under high temperature. NEOFLON PFA has excellent moldability for easy processing by extrusion to the same degree as general thermoset plastics.
It is used where purity is important, such as in semiconductor wafer baskets, piping couplings and non-corrosive linings. Furthermore, in response to the high purity, high density needs of LSIs, Daikin has developed a moldable PFA that greatly reduces fluorine ion concentration and excels in surface flatness. Needless to say, demand is growing.
In addition to moldable materials, powder paint and film for producing linings without pinholes are also available.
Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON PFA
copolymer of tetrafluoroethylene and perfluoroalkyl vinyl ether(PFA)
Pellets


Jigs for semiconductor,electrical wire,film,tube,corrosion-proof lining,applications requiring mechanical strength
Coating Powders


Corrosion-proof lining and insulation-coating materials
Film


Electric wire,insulating sheet materials,corrosion-proof lining,mold release film
(1)For molding(2)For coating(3)For additive(4)Other use

NEOFLON FEP (FEP)
Except for the fact that heat resistance is slightly low at a 200℃maximum temp. for continuous use, FEP has almost the same characteristics as PTFE. It offers the same workability as PFA and can be used in injection molding to the same degree as general thermoset plastics. It is widely used in computer wiring, LAN cables and other wiring applications that require high speed communications, because of its good dielectric characteristics, flame retarding property (low smoke generation) and workability. Also, it is used as film in solar collector covers and mold release agent with polyurethane, because of its weather resistance and transparency. It is also available as powder paints for producing pinhole-less linings.
Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON FEP
copolymer of tetrafluoroethylene
and hexafluoropropylene
(FEP)
Pellets


Tube,film,electrical wire
Dispersions


Insulation-coating materials,non-cohesive coating materials.mold releasing film
Coating Powders


Electrical wire,insulating sheet materials
Film


Release film, insulating sheet, electric and corrosion resistant lining, stain resistant interior material, corrosion-proof lining,soil release interior finish
(1)For molding(2)For coating(3)For additive(4)Other use

NEOFLON ETFE (ETFE)
In terms of heat resistance, ETFE is about middle of the spectrum with a 150℃maximum temp. for continuous use. It offers the same workability as PFA and can be used in injection molding to the same degree as general thermoset plastics. Its characteristics are best exhibited in applications that require mechanical toughness, chemical and heat resistance, and electrical characteristics. It is used in automotive fuel hose linings of low flow lines, chemical pump housings and robot wiring.
Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON ETFE
copolymer of tetrafluoroethylene and ethylene(ETFE)
Pellets


Electrical wire,corrosion-proof lining material,tube
Film


Window mold of automobiles
(1)For molding(2)For coating(3)For additive(4)Other use

NEOFLON PVDF (PVDF)
In terms of heat resistance, PVDF is about middle of the spectrum with a 150℃maximum temp. for continuous use. It offers excellent mechanical characteristics and a dielectric properties (piezoelectricity and pyroelectricity) not seen with other types of fluoroplastics
Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON PVDF
Polyvinylidene fluoride Abbreviation(PVDF)
Pellets


Pipe,valve,pump,electrical wire,tube,film,sheet lining
(1)For molding(2)For coating(3)For additive(4)Other use

NEOFLON PCTFE (PCTFE)
In terms of heat resistance, PCTFE is about middle of the spectrum with a 150℃maximum temp. for continuous use Chemical resistance is slightly less robust than other fluoroplastics, but it offers excellent mechanical characteristics. It can be used in press and extrusion molding. Molded parts are used in physiochemical instruments, pumps and couplings, while films are used in moisture prevention covers.
Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON PCTFE
Polychlorotri-
fluoroethylene
(PCTFE)
Molding Powders


Packing,gasket,piping material
moisture resistant film(for EL covers and packaging of chemicals)
(1)For molding(2)For coating(3)For additive(4)Other use

Name
Formula
Type
(1) (2) (3) (4) Major application
NEOFLON FMC Pellets


Parts for sliding that need mechanical strength.
POLYFLONMPA Powders


Flame retardant additive for plastics
POLYFLON PTFE low polymers Powders


Lubricant, extreme pressure additive,
Dispersion

Aerosol


(1)For molding(2)For coating(3)For additive(4)Other use
Products marked withe(*):partly contain articles of product numbers which require export permits.


Property ASTM test method Test
condition
Unit POLYFLON PTFE NEOFLON PFA NEOFLON FEP
Physical properties

Specific gravity

D792 2.13-2.22 2.12-2.17 2.12-2.17

Water absorption

D570 24h 1/3"t % <0.00 <0.01 <0.01

Mold shrinkage

cm/cm 0.02-0.05 0.04 0.03-0.06

Contact angle

Angle to
level
degree 110 115 114
Thermal property

Thermal conductivity

C177 W/m K
/cm
0.25 - 0.25

Coefficient of linear thermal expansion

D696 23-60 1/ 10ラ10-5 12ラ10-5
(+20-+100)
(8.3-10.5)ラ10-5
(-50-+100)

Melting point

327 302-310 270

Melting viscosity

p 1010-1012
(340-380)
103-104
(380)
4ラ103-104
(380)

Maximum temp. for continuous use

260 260 200
Mechanical properties

Tensile strength

D638 23 MPa 20-45 27-35 19-22

elongation

D638 23 % 200-450 280-400 250-330

Compression strength

D695 1% defor-
mation,
25
MPa 5-6 5-6 5-6

Tensile modulus

D638 23 MPa 392 451 343

Tensile modulus

D790 23 MPa 490-588 647-686 539-637

Impact strength

D256 23lzod J/m 160 No break No break

Hardness

Durometer ShoreA D50-D65 D60 D55

Deformation under load

D621 100,
7MPa,
24h
% 5.0 0.4 5.0

Deformation under load

D621 25,
14MPa,
24h
% 7.0 2.7 3.0

Stric friction coefficient

Coasted-
steel
surface
0.02 0.05 0.05
Physical properties

Dielectric constant

D150 103Hz 2.1 2.1 2.1

Dielectric constant

D150 106Hz 2.1 2.1 2.1

Dielectric dissipation factor

D150 103Hz <1ラ10-5 1ラ10-5 6ラ10-5

Dielectric dissipation factor

D150 106Hz 2ラ10-5 3ラ10-4 5ラ10-4
Dielectric breakdown strength D149 Short time
3.2mm
MV/m 19 20 20-24

Volume resistance

D257 cm >1018 >1018 >1018
 

Chemical resistance

Excellent Excellent Excellent
Weatherability Excellent Excellent Excellent
Combustibility D2863 Oxygen
limiting
Oxygen
Index
% >95 >95 >95

Property ASTM test method Test
condition
Unit NEOFLON ETFE NEOFLON PCTFE NEOFLON PVDF
Physical properties

Specific gravity

D792 1.70-1.86 2.10-2.14 1.76-1.78

Water absorption

D570 24h 1/3"t % <0.1 <0.00 0.04

Mold shrinkage

cm/cm 0.015-0.020 0.03-0.04 0.014

Contact angle

Angle to
level
degree 96 84 82
Thermal property

Thermal conductivity

C177 W/m K
/cm
0.24 0.20-0.22 0.13

Coefficient of linear thermal expansion

D696 23-60 1/ (5-9)ラ10-5 (4.5-7.0)ラ10-5 4.2ラ10-5

Melting point

260 210-212 173-175

Melting viscosity

p 104-105
(300-330)
107(230) 2ラ103-105
(210-270)

Maximum temp. for continuous use

150 120 150
Mechanical properties

Tensile strength

D638 23 MPa 40-50 31-41 39-59

elongation

D638 23 % 420-460 80-250 300-450

Compression strength

D695 1% defor-
mation,
25
MPa 11 9-12 13-14

Tensile modulus

D638 23 MPa 490-784 1,029-2,058 784-1,960

Tensile modulus

D790 23 MPa 882-1,372 1,274-1,764 1,372-1,764

Impact strength

D256 23lzod J/m No break 133-144 192-214

Hardness

Durometer ShoreA D75 D80 D75-D85

Deformation under load

D621 100,
7MPa,
24h
% 5.4 2.6 2.4

Deformation under load

D621 25,
14MPa,
24h
% 2.3 0.2 0.7

Stric friction coefficient

Coasted-
steel
surface
0.06 0.08 0.4
Physical properties

Dielectric constant

D150 103Hz 2.6 2.3-2.7 7.72

Dielectric constant

D150 106Hz 2.6 2.3-2.5 6.43

Dielectric dissipation factor

D150 103Hz 8ラ10-4 (2.3-2.7)ラ10-2 1.9ラ10-2

Dielectric dissipation factor

D150 106Hz 5ラ10-3 1ラ10-2 0.159
Dielectric breakdown strength D149 Short time
3.2mm
MV/m 16 20-24 10

Volume resistance

D257 cm >1016 >1016 2ラ1014
 

Chemical resistance

Excellent Excellent Good
Weatherability Excellent Excellent Excellent
Combustibility D2863 Oxygen
limiting
Oxygen
Index
% 31 >95 43

IMPORTANT NOTICE: The information contained herein is based on technical data and tests we believe to be reliable and is intended for use by persons having technical knowledge and skill, solely at their own discretion and risk. Since conditions of use are outside of our control, we assume no responsibility for results obtained or damages incurred through application of the data given: and the publication of the information herein shall not be understood as permission or recommendation for the use of our fluorocarbon compounds in violation of any patent or otherwise. We only warrant that the product conforms to description and specification, and our only obligation shall be to replace goods shown to be defective or refund the original purchase price thereof.

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